UJI EFEKTIVITAS ADSORPSI BIOADSORBEN SERBUK KULIT BUAH SUKUN (Artocarpus atilis) TERHADAP LOGAM BERAT SENG (Zn) PADA LIMBAH LABORATORIUM INDUSTRI FARMASI

Siti Nurmalah Riskiyani Hayati (1) , Hesty Nuur Hanifah (2) , Ginayanti Hadisoebroto (3)
(1) jurusan farmasi universitas Al-Ghifari,
(2) Universitas Al-Ghifari,
(3) Jurusan Farmasi Universitas Al-Ghifari
https://doi.org/10.53675/jsfar.v11i1.1119
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Issue
Vol. 11 No. 1 (2023): SABDARIFFARMA
Submitted
2023-07-31
Published
2023-08-01
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Abstract

ABSTRAKKulit buah sukun memiliki banyak kandungan kimia seperti hidrokoloid polisakarida, saponin, polifenol, asam hidrosianat, asetilkolin, tanin, riboflavin, flavonoid dan selulosa. Kulit  buah sukun mengandung selulosa dengan kadar 17,59%. Selulosa merupakan polisakarida yang mengandung gugus –OH sehingga dapat digunakan sebagai adsorben untuk logam berat seperti logam Zn. Tujuan dari penelitian ini untuk mengetahui efektivitas kulit buah sukun sebagai adsorben terhadap penyerapan logam Zn pada kondisi pH, waktu kontak dan massa optimumnya, serta untuk mengetahui model kinetika adsorpsi yang tepat pada penyerapan logam Zn yang terdapat pada limbah cair industri farmasi. Proses optimasi pH, waktu kontak dan massa ditentukan menggunakan desain uji faktorial dengan aplikasi Design Expert. Penentuan kadar Zn pada sampel dilakukan menggunakan Spektrofotometer Serapan Atom (SSA). Hasil penelitian menunjukkan bahwa % efektivitas penyerapan Zn tertinggi yaitu 94,29% pada pH 8, waktu kontak 45 menit dan massa adsorben 125 mg. Kinetika adsorpsi penyerapan logam Zn pada 100, 125 dan 150 mg mengikuti model kinetika orde 0.Kata kunci : Adsorpsi, Serbuk, Kulit Buah Sukun, Efektivitas, Kinetika AdsorpsiABSTRACTBreadfruit peel has many chemical constituents such as hydrocolloid polysaccharides, saponins, polyphenols, hydrocyanic acid, acetylcholine, tannins, riboflavin, flavonoids and cellulose. Breadfruit peel contains 17.59% cellulose. Cellulose is a polysaccharide that contains –OH groups so that it can be used as an adsorbent for heavy metals such as Zn metals. The purpose of this study was to determine the effectiveness of breadfruit peel as an adsorbent for the absorption of Zn metals at optimum conditions of pH, contact time and mass, and to determine the appropriate adsorption kinetics model for the absorption of Zn metals found in pharmaceutical industrial wastewater. The process of optimizing pH, contact time and mass is determined using a factorial test design with the Design Expert application. Determination of Zn levels in the samples was carried out using Atomic Absorption Spectrophotometry (AAS).The results showed that the highest % effective absorption of Zn metal absorption was 94.29% at pH 8, contact time of 45 minutes and adsorbent mass of 125 mg. The adsorption kinetics of Zn metal absorption at 100, 125 and 150 mg followed the 0-order kinetics model.Keywords : Adsorption, Powder, Breadfruit Peel, Effectiveness, Adsorption Kinetics

Authors

Siti Nurmalah Riskiyani Hayati
jurusan farmasi universitas Al-Ghifari
Hesty Nuur Hanifah
Universitas Al-Ghifari image/svg+xml
http://orcid.org/0000-0003-3541-4193 (unauthenticated)
Jurusan Farmasi
Ginayanti Hadisoebroto
Jurusan Farmasi Universitas Al-Ghifari

How to Cite

UJI EFEKTIVITAS ADSORPSI BIOADSORBEN SERBUK KULIT BUAH SUKUN (Artocarpus atilis) TERHADAP LOGAM BERAT SENG (Zn) PADA LIMBAH LABORATORIUM INDUSTRI FARMASI. (2023). Jurnal Sabdariffarma: Jurnal Ilmiah Farmasi, 11(1), 56-66. https://doi.org/10.53675/jsfar.v11i1.1119

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